Appropriate and Sustainable Materials

Introduction

Polymers is one of the most dominant material used in the industry as majority of the products today uses polymer, However the resources is limited and each time polymers is recycled it degrades in quality so it is not a sustainable resource. So a replacement material is absolutely required to replace plastics.

Another material that is high on demand is aluminium, there is a large abundance in Aluminium but the ore is processed from is bauxite and that uses a lot of energy to achieve to the aluminium form.

The goal is to be able to locate a material, which will have versatile properties, which can replace both materials.

 

Research

When selecting a material to replace the current, I have come across Shrilk which is a material made of crustacean shells, so I had got in contact with the scientist Dr Javier Fernandez, which designed this material.

Environmental Shrilk

Background

The history of Shrilk is that it originally started out of people using Chitin (glucose from crustacean shells) as a fertilizer produce. However, scientist in Harvard University had taken interest of the molecular structure of Chitin as it has a very strength and toughness, which is comparable to Aluminium Alloys and the flexibility of most plastics. Therefore, the aim that was set for them is to try to harness the raw material and make it a mass produced industrial material.

If the scientists are able to reproduce the structure of the insect shell, it would be able to achieve certain heights as it will be able to replace a lot of materials used in society today. Also there will be a large abundance of chitin available as there are many shrimp farms in the world and even though it is bad for the environment to create Shrimp farms, it is still needed as there is a large demand of shrimps worldwide in the food industry. Therefore if Shrilk can be produced, it will lessen the negative impact of Shrimp farms as it will be used to reduce the use of polymers.

Insect cuticles, crusta­cean shells, and other chitin-containing living materials have an unusual strength and toughness and it is because of the complex structural interactions between chitin polysaccharides and proteins in these materials. Chitin is also second most abundant material in the world as it is the glucose molecule found in exoskeleton.

It has been difficult to engineer artificial materials that reproduce the exact properties of the Crustaceans because during the moulding of Chitosan the processed version of Chitin, the material had no 3D structure and could not hold itself up. However, soon Fibroin, which is a protein like structure found in silk, was used in Chitosan to give it a more 3D physical structure, however, it did not display the desired strength properties instead was weaker than Chitosan.

The reason for the poor material properties of chitosan-silk composites is that they are disorganized con­glomerates, that is, they fail to regenerate the phase-separated laminar arrangement of the closely apposed chitin and protein found in natural cuticle.

Life Cycle Assessment

To show that Shrilk is a versatile material and is able to replace a current product that uses polymers and aluminium, the LCA assessment have been made for the Paraglider which will be manufactured for a batch production in industry, and there will be comparison between the two material selections.

Production with Material A
Material or Processes Amount Indicator Result
Aluminium 100% Recycled 1000 60 60000
PVC (Flexible) 1000 240 240000
Total 2000 300 300000
 Use with Material A
Process Amount Indicator Result
Bending Aluminium 7000 0.000047 0.329
Extrusion Aluminium 7000 72 72000
Spot Welding 21000 2.7 56700
Shearing/Stamping Aluminium 15000 0.000036 0.54
Calandering PVC Foil 1000 3.7 3700
Heat Coal 10000 4.2 42000
Truck 40T 400000 15 6000000
Total 461000 97.600083 6174400.869
Disposal with Material A    
Material and types of processing Amount Indicator Result
Recycling PVC 1000 -250 -25000
Total 1000 -250 -25000
Total 464000 147.6 6449400.869

Shows the LCA for material A’s Paraglider

 

 

 

Production with Shrilk
Material or Processes Amount Indicator Result
Chemical Organic 1000 99 99000
H2SO4 7000 22 154000
Water Demineralized 14000 0.026 364
Total 22000 121.026 253364
Use with Shrilk
Process Amount Indicator Result
Heat Coal (Industriale Furnace) 6000 4.2 25200
Extrusion -Aluminium 3500 72 252000
Injection Moulding – 2 1000 44 44000
Truck 40T 175000 15 2625000
Total 185500 135.2 2946200
Disposal with Shrilk
Material and types of processing Amount Indicator Result
N/A N/A N/A N/A
Total N/A N/A N/A
Total 207500 256.226 3199564

Shows the LCA for Shrilk’s Paraglider

 

As shown from the facts and figures from the LCA, material A uses more energy compared to Shrilk as well as, there is more needed processes for material A, meaning that if both material had to build a factory and all the set up costs for the equipment, Shrilk would be more cost effective as the processes are less plus the size of the factory would not be required to large compared to material A which needs more room to house the manufacturing tools and equipment.

Another benefit is the disposal stages as when recycling the material A parts it will require a lot of energy to return the parts in to mouldable form. Whereas Shrilk can be thrown in landfill or used as fertilizers and it will break down by itself over time as it is 100% biodegradable.

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